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The structure of the adduct from N-[p-bromobenzyl]-isoquinolinium bromide and carbon disulfide

✍ Scribed by John E. Baldwin; Mildred C. McDaniel; M.Gary Newton; Iain C. Paul

Publisher: Elsevier Science
Year: 1966
Tongue: French
Weight: 105 KB
Volume: 7
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)76043-6

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✦ Synopsis

N-[Benzyl]isoquinolinium halides and carbon disulfide heated in strongly basic aqueous dioxane give adducts which have been assigued structure I (2). The available evidence (2) is equally consistent with the alternative formulation II. For an analogous base-catalyzed reaction between an N-[benayll-5,4-dihydroisoquinolinium halide and carbon disulfide, the structural ambiguity in the edduct as to the direction of addition on the CS double bond was clearly recognized (5).

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