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The structure of the adduct from 3-diazobutanone and carbon disulfide

✍ Scribed by J.A. Kapeck; J.E. Baldwin; I.C. Paul

Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
45 KB
Volume
9
Category
Article
ISSN
0040-4039

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✦ Synopsis

In Table for bond angle S(l)-C(2)-S(3) read 100.6' instead of 106.6O

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The structure of the adduct from 3-diazo
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✍ Jon A. Kapecki; John E. Baldwin; Iain C. Paul πŸ“‚ Article πŸ“… 1967 πŸ› Elsevier Science 🌐 French βš– 156 KB

Printed in great Britain\* (Received in USA 21 AuLugust 1967) 3-Diazo?Jutaaoneinrefluxing carbon disulfide afforda anadduct C&&$\*ldBichm beem assigned stnxture Ia (or its gemetric iraner) (2), a fomulation analogous to Ib

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N-[Benzyl]isoquinolinium halides and carbon disulfide heated in strongly basic aqueous dioxane give adducts which have been assigued structure I (2). The available evidence (2) is equally consistent with the alternative formulation II. For an analogous base-catalyzed reaction between an N-[benayll-5