The structure of hexapotassium disodium hexatungstoplatinate(IV) dodecahydrate, K6Na2[PtW6O24].12H2O
โ Scribed by Lee, U. ;Ichida, H. ;Kobayashi, A. ;Sasaki, Y.
- Book ID
- 111858934
- Publisher
- International Union of Crystallography
- Year
- 1984
- Tongue
- English
- Weight
- 313 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0108-2701
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The symmetry of the hexatungstoplatinate(IV) anion in Na 8 [PtW 6 O 24 ]ร26H 2 O is C i (1), which is different from the D 3d (3m) and S 6 (3) symmetry found in K 6 Na 2 [PtW 6 O 24 ]ร-12H 2 O and (CH 6 N 3 ) 8 [PtW 6 O 24 ], respectively. However, this change in symmetry does not signiยฎcantly affec
A new compound containing polyoxovanadoborate anion was synthesized and characterized by single-crystal X-ray diffraction analysis. A water molecule at the center of the anion was precisely determined. The crystals of the new compound belong to the monoclinic system, space group P2 1 /n with a๏ผ1.350