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Structure of pentasodium trihydrogenhexatungstoplatinate(IV) icosahydrate, Na5[H3PtW6O24].20H2O

✍ Scribed by Lee, U. ;Kobayashi, A. ;Sasaki, Y.


Book ID
114501513
Publisher
International Union of Crystallography
Year
1983
Tongue
English
Weight
306 KB
Volume
39
Category
Article
ISSN
0108-2701

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Pentapotassium tri­hydrogenhexatungstopl
✍ Lee, Uk 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 317 KB

The [H 3 PtW 6 O 24 ] 5À anion has close to 3m symmetry, with PtÐ O bond lengths in the range 1.97 (1)±2.01 (1) A Ê and WÐO bond lengths in the ranges 1.72 (1)±1.78 (1) (O t ), 1.91 (1)± 1.96 (1) (O b ) and 2.14 (1)±2.33 (1) A Ê (O c ), where O t are terminal atoms, O b bridge two W atoms, and O c t

Octasodium hexatungstoplatinate(IV) hexa
✍ Lee, Uk ;Joo, Hea-Chung 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 617 KB

The symmetry of the hexatungstoplatinate(IV) anion in Na 8 [PtW 6 O 24 ]Á26H 2 O is C i (1), which is different from the D 3d (3m) and S 6 (3) symmetry found in K 6 Na 2 [PtW 6 O 24 ]Á-12H 2 O and (CH 6 N 3 ) 8 [PtW 6 O 24 ], respectively. However, this change in symmetry does not signi®cantly affec