Acceleration of a homolytic O-O bond cleavage by participation of a neighboring sulfur atom has been very clearly established in m-butyl o-methylthioperoxybenzoate (2) which decomposes ~a. lo4 times as fast as the parent peroxybensoate at 600~ in chlorobensene. The rate-determining step for the clea
The structure of alkoxyfluoroalkyl radicals as studied by M.O. and computer simulation of polycrystalline spectra
β Scribed by A. Faucitano; A. Buttafava; F. Martinotti; G. Caporiccio; C.T. Viola
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 72 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0022-1139
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The initial st3ges of salvation and c~srdlizatron were studted in phcnct-(!lz0>, .md (phenolf,r hy the uw ai the mdss-\_\elected MPI methcd in d supersonic free jet. The spectral position exhibits ;Ln irregular shift b> the change of the cluster \ize\_ x~hich ts interpreted in te:ms oi the role of p