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The structure and ring-puckering vibration of thietane as studied by 1H and 13C NMR spectra of the oriented molecule

✍ Scribed by J. Jokisaari; J. Kuonanoja; A.-M. Häkkinen

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
297 KB
Volume
14
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The ^1^H and ^13^C NMR spectra of partially oriented thietane have been recorded and analysed. The molecular structure was determined assuming the molecule to be planar and rigid. Because of the unsatisfactory fit of the dipolar coupling constants, a model which also takes into account the ring‐puckering vibration was applied. This model leads to a better fit, but also to long CH distances. Consequently, it seems that the one‐dimensional ring‐puckering model does not on its own explain the differences between the experimental and calculated coupling constants.

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