✦ LIBER ✦

On the structure of o-methylthiobenzoyloxy radical as revealed by CIDNP spectra and CNDO/2 MO calculations

✍ Scribed by Waro Nakanishi; Shōgo Koike; Makoto Inoue; Yoshitsugu Ikeda; Hiizu Iwamura; Yuzo Imahashi; Hiroshi Kihara; Masahiro Iwai

Publisher: Elsevier Science
Year: 1977
Tongue: French
Weight: 244 KB
Volume: 18
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)92556-0

No coin nor oath required. For personal study only.

✦ Synopsis

Acceleration of a homolytic O-O bond cleavage by participation of a neighboring sulfur atom has been very clearly established in m-butyl o-methylthioperoxybenzoate (2) which decomposes ~a. lo4 times as fast as the parent peroxybensoate at 600~ in chlorobensene. The rate-determining step for the cleavage is described by the anchimerically assisted structure z. 2) CH3.S 0

📜 SIMILAR VOLUMES

Structural changes as a function of tors

Structural changes as a function of torsional motion studied by ab initio calculations part 4. The dependence of the dynamic behavior of the structural parameters for H2O2 and H2S2 on basis sets and comparison with experimental results

✍ Svein Samdal; Vladimir S. Mastryukov; James E. Boggs 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 356 KB