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The structure and steric directivity of the reaction of thiyl anions with vinylacetylene

✍ Scribed by E. N. Prilezhaeva; V. N. Petrov

Book ID
112488246
Publisher
Springer
Year
1966
Tongue
English
Weight
73 KB
Volume
15
Category
Article
ISSN
1573-9171

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Hydrogen bonding between vinylacetylene
Hydrogen bonding between vinylacetylene and HF: the role of steric effects in the geometry of vinylacetylene…HX complexes
✍ Z. Kisiel; P.W. Fowler; A.C. Legon πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 545 KB

The rotational spectrum of a hydrogen-bonded dimer between vinylacetylene (H,C=CHC=CH) and HF has been obtained with a pulsed-nozzle Fourier-transform mxrowave spectrometer. Analysis of the derived spectroscopic constants shows that the HF molecule attaches preferentially to the triple bond in viny