Structural and steric course of the nucleophilic addition reaction of thiols to vinylacetylene
β Scribed by E. N. Prilezhaeva; V. N. Petrov; A. N. Khudyakova
- Book ID
- 112434933
- Publisher
- Springer
- Year
- 1968
- Tongue
- English
- Weight
- 474 KB
- Volume
- 17
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
Six-membered ring ketones such as 4 butyl-cyclohexanone, I, are attacked by nucleophiles (e.g., Grignard reagents or metal hydrides) from two different sites giving rise to products E with an equatorial OH group, and A with.an axial OH group. The ratio of the amounts the rate constants 1, 2) have re
## Abstract The first intramolecular nucleophilic addition of a thiol to a fullerene double bond is reported. Whereas the reaction of cysteine (**4**) or cystine (**11**) with formaldehyde and [60]fullerene in chlorobenzene at reflux afforded the new compound **10** bearing a thiazolidine moiety fu