Vinyliodonium salts 2 were synthesized from vinylsilanes 1 by the reaction with iodosylbenzene and triethyloxonium tetrafluoroborate. The reaction-occurs stereospecifically with retention of configuration. Vinyliodonium salts 2 are highly effective as the activated species of vinyl iodides. Thus, a
The stereospecific synthesis of vinyl halides using a vinylsilane as the synthetic precursor
โ Scribed by R.Bryan Miller; Thomas Reichenbach
- Book ID
- 104234596
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- French
- Weight
- 170 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Although much is known about the properties and chemistry of vinylsilanes,1~2 relatively little use has been made of them in organic synthesis.s We describe here the use of a vinylsilane as the precursor to the stereospecific synthesis of vinyl halides.
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