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The stereoselective synthesis of a hydroazulenic precursor of guaiol

โœ Scribed by James A. Marshall; Andrew E. Greene

Book ID
104247502
Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
185 KB
Volume
12
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

The synthesis and selective degradation
The synthesis and selective degradation of guaiol
โœ James A. Marshall; Andrew E. Greene; Ronald Ruden ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 163 KB

In the previous report we described the stereoselective synthesis of the acetate deriva-

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โœ Marshall, James A.; Greene, Andrew E. ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 603 KB
The synthesis of (+)-hedycaryol, startin
The synthesis of (+)-hedycaryol, starting from natural (โˆ’)-guaiol
โœ Adriaan J. Minnaard; Joannes B.P.A. Wijnberg; Aede de Groot ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 795 KB

## Starting from the readily available (-)-guaiol the germacrane sesquiterpene I+)hedycayol can be synthesized in a 7 steps reaction sequence in an overall yield of 16%. Additionally, (+)-peudesmol has been synthesized, also starting from I-)-guaiol.