The Stereochemistry of the Lithium-Ammonia Reduction of α,β-Unsaturated Ketones
✍ Scribed by Stork, Gilbert.; Darling, S. D.
- Book ID
- 127188420
- Publisher
- American Chemical Society
- Year
- 1964
- Tongue
- English
- Weight
- 1002 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
## Abstract Eleven structurally different α, β‐unsaturated ketones were subjected to the __Clemmensen__ reduction under anhydrous conditions using amalgamated zinc, hydrogen chloride in a solution of ethyl ether, and acetic anhydride. In all cases but one the formation of cyclopropyl acetates was o
## Bromination 7.11~ dibrtimidcs 7-12 haw bccn synthesized by addition of bromint to exocyclic ell-unsaturated ketones 1-6. The rclative configurations and the swcocliemistry of the products have been dctermined by N M K methods. Bromination ol3-hcnzylideneflilwnonc (3) and its thio analogue 5 pro