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The stereochemistry of the hydroboration rearrangement.

โœ Scribed by Leslie D Field; Stephen P Gallagher


Book ID
108382642
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
201 KB
Volume
26
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


Stereochemistry of the hydroboration rea
โœ Kabalka, George W.; Bowman, Newell S. ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 294 KB
Stereochemistry of Hydroboration
โœ Hassner, Alfred; Pillar, Conrad ๐Ÿ“‚ Article ๐Ÿ“… 1962 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 239 KB
Stereochemistry of the hydroboration of
โœ Kabalka, George W.; Newton, Ray J.; Jacobus, John ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 388 KB
Stereochemistry in the hydroboration of
โœ Ian Fleming; Nicholas J Lawrence ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 251 KB

The hydroboration of allylsilanes is highly stereoselective in the sense (3 -t 4 and 6 + .I), especially with 9-BBN as the hydroborating reagent. The products can be converted stereospecifically into 1,3-diol derivatives (5 and 6). Allylsilanes usually react with electrophiles in the stereochemica