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Stereochemistry of Hydroboration

โœ Scribed by Hassner, Alfred; Pillar, Conrad

Book ID
126075712
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
239 KB
Volume
27
Category
Article
ISSN
0022-3263

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The hydroboration of allylsilanes is highly stereoselective in the sense (3 -t 4 and 6 + .I), especially with 9-BBN as the hydroborating reagent. The products can be converted stereospecifically into 1,3-diol derivatives (5 and 6). Allylsilanes usually react with electrophiles in the stereochemica