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Stereochemistry in the hydroboration of allylsilanes

โœ Scribed by Ian Fleming; Nicholas J Lawrence

Book ID
104221249
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
251 KB
Volume
29
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The hydroboration of allylsilanes is highly stereoselective in the sense (3 -t 4 and 6 + .I), especially with 9-BBN as the hydroborating reagent.

The products can be converted stereospecifically into 1,3-diol derivatives (5 and 6).

Allylsilanes usually react with electrophiles in the stereochemical sense (1). 2-4 We now report that they generally undergo hydroboration with the same stereochemistry, so that it is E+ R'sSi

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