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The Stereochemistry of Sulfoxides

✍ Scribed by K. Mislow


Publisher
John Wiley and Sons
Year
1965
Tongue
English
Weight
133 KB
Volume
4
Category
Article
ISSN
0044-8249

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✦ Synopsis


thin-layer plates, removal of the spots and extraction of the silica gel with methanol containing 5 % of concentrated ammonia solution are recommended. After excitation with the 365 mu Hg line, the intensity of fluorescence of the extract is determined at 520 mp for DANS-amides and at 530 m p for phenol-and pyrocatechol-amine derivatives. Reproducibility is 3-5 for concentrations of 2x 10-10 mole/cm3.


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Stereochemistry of a [2,3] sigmatropic a
✍ R.W. Hoffmann; R. Gerlach; S. Goldmann πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 207 KB

3,3lSigmatropic rearrangements follow a well defined stereochemistry') and lend themselves for asymmetric syntheses 2) . Much less is known about the stereoche-3) mistry of [2,3]sigmatropic rearrangements , which also show high stereoselecti-vities4', 5) being even stereospecific in some cases . We