The Stereochemistry of Sulfoxides
β Scribed by K. Mislow
- Publisher
- John Wiley and Sons
- Year
- 1965
- Tongue
- English
- Weight
- 133 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0044-8249
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β¦ Synopsis
thin-layer plates, removal of the spots and extraction of the silica gel with methanol containing 5 % of concentrated ammonia solution are recommended. After excitation with the 365 mu Hg line, the intensity of fluorescence of the extract is determined at 520 mp for DANS-amides and at 530 m p for phenol-and pyrocatechol-amine derivatives. Reproducibility is 3-5 for concentrations of 2x 10-10 mole/cm3.
π SIMILAR VOLUMES
3,3lSigmatropic rearrangements follow a well defined stereochemistry') and lend themselves for asymmetric syntheses 2) . Much less is known about the stereoche-3) mistry of [2,3]sigmatropic rearrangements , which also show high stereoselecti-vities4', 5) being even stereospecific in some cases . We
To date, a nutier of 'H NI(R methods have been developed for the assignment of configuration and conformation in cyclic sulfoxides.