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The Stereochemistry of Rings A and B in 6-substituted Δ4-3-ketosteroids. A study of H1 allylic spin-spin coupling in rigid systems.

✍ Scribed by D.J. Collins; J.J. Hobbs; S. Sternhell

Publisher: Elsevier Science
Year: 1963
Tongue: French
Weight: 332 KB
Volume: 4
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)90606-9

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✦ Synopsis

JXE endocrinological importance of a number of natural' and n syntheticL 6-substituted steroid hormones makes their stereochemistry of special interest, We have prepared a number of 6-substituted-A4-cholestene-3-ones and examined their NkR spectra to determine whether a general correlation could be made between the configuration (and conformation) at the &position and the character of the NXR signal attributed to the vinylic proton at C4.

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