A study of the low spin ⇋ high spin transitions in [Fe(phen)2(NCSe], [Fe(bipy)2(NCS)2], and [Fe(isoxazole)6](ClO4)2 complexes using 1H nuclear magnetic resonance
✍ Scribed by Biswanath Maiti; Bruce R McGarvey; P Sambasiva Rao; Lindsay C Stubbs
- Publisher
- Elsevier Science
- Year
- 1983
- Weight
- 756 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0022-2364
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📜 SIMILAR VOLUMES
The transition temperature of [Fe@hen)z(NCS)z ] measured by susceptibility measurements in an applied tield of 1 T shifts by -0.11 f 0.04 K when the field is increased to 55 T. This shift is predicted on the basis of the known magnetic susceptibility and specific heat data.
## Abstract The X‐ray structures of the novel spin crossover complex [Fe(pmea)(NCS)~2~] with pmea = (bis[(2‐pyridyl)methyl]‐2‐(2‐pyridyl)ethylamin) were determined in its low‐spin (singlet, LS) and high‐spin state (quintet, HS) and compared with the optimized geometries produced by BP86 calculation