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The stereochemistry of albofungin

✍ Scribed by A.I. Gurevich; T.I. Deshko; G.A. Kogan; M.N. Kolosov; V.V. Kudryashova; V.V. Onoprienko

Publisher: Elsevier Science
Year: 1974
Tongue: French
Weight: 174 KB
Volume: 15
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)91747-2

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✦ Synopsis

Alboiangin, en antibiotlo from Aotinoaycee glbua var. fumzatuta (I), had reoexrtly been shown to have the structure I (2). loar we have found it to poseem the abeolute etemochemietry depleted by formula I. t The heliclty of the BDJG riog eyetern of the antibiotlo and henoo the configuration of the C-9 centre was detemised from CD ape&m of albofungin end its degradation products, eepeciw albofungol (IIa), in a menner similar to the exolton chiraliiq method of Harada and Bakanlahi (3). The inherently diesymmerbric chromophore of albofungo1GI.a) oompriees abenseno3.dandenieo-

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