The tri-substituted (2,3)-double bond in allohimachalol (1) undergoes autoxidation in the presence of singlet molecular oxygen, resulting in tertiary and secondary allylic hydroperoxides 6 and 7. These autoxidation products may then participate in complex rearrangement reactions to yield seccallohim
The stereochemistry of allohimachalol
β Scribed by Ashok G. Bajaj; Sukh Dev; Bruce Tagle; Joshua Telser; Jon Clardy
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- French
- Weight
- 127 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0040-4039
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