On warming at a rate of 4 "C/min in a sealed testing vessel (Mettler thermoanalyzer TA 2000) benzyl(triethy1)ammonium permanganate explodes violently at cu. 120 "C with liberation of about 350 kJ/mol heat. The compound also decomposes violently at lower temperatures, but only after expiration of a c
The stability of permanganate solutions
β Scribed by Cohen, J. U. ;Oddy, R. W.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1890
- Weight
- 231 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0368-4075
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β¦ Synopsis
~'IIERF: is iio ntiiilyticnl process wlticli 110s Iiiid more clcttinnds tiinclc iipoii it iii rccciit years thnn 11 riipid niid reliiible :iictliod for cstiiiintiiig orgiiiiic iiitropcii. Tlic IICW process of Kjcldntil iippcnrs to Iiirvc siipplictl tlicsc rcqiiircnteitts. Tliiit of N'nnklyti is oliviously iitiitlcilii:i~c, cspcciully ns it 1i:is been slio\vn that iiiumoniu is dceomposctl liy nlkiiliitc pcriiiniignit~itc 011 long boiling. l)iiiiius' iiietliod Iins stood the test of time. I t nppenrcd to iis iiitercsting to in:ikc it coiupnrison of tliese tlirec methods, niicl to cletcrniine how iiciirly tlicy iigrccd. Colourless isitigliiss wis selcctcd iis n typical iilliuiniiioid siibstniicc. It wis powlercd nttd dried iiud iiniilyscd 1iy Tltc tirinlyscs by 1)iiiiiiis' tiiethod, which iiec$s no tllC tlirec proccsses. dcscriptioti, giivc the folloiviiig rcsults :-'1605
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