Aqueous acid solutions of nitric oxide (NO) are used as a source for this species in chemical and biological experiments. To utilize known quantities of NO, it is necessary to determine the escape rate of NO from these solutions. Escape rates at constant temperature are concentration dependent. The
The stability of carotene solutions towards oxidation
β Scribed by McGillivray, W. A.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1950
- Weight
- 337 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0368-4075
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β¦ Synopsis
Abstract
The rates of decomposition of carotene in liquid paraffin and in hydrogenated coconut oil under accelerated conditions at 100Β° C. with forced aeration have been investigated. In the case of paraffin containing less than 50ΞΌg./ml., the rate is shown to be proportional to the log. of the concentration. The spectral changes occurring during oxidation at 100Β° c. and irradiation at room temperature hare also been followed and it is shown that the estimation of vitamin A in the presence of oxidized carotene by direct spectroscopic measurement is possible provided a simple correction is applied. Hydrogenated Coconut oil is suggested as a suitable solvent for carotene in feeding trial work.
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## Abstract The rate of hydrolysis of __N__βmethylβ__N__βnitrosoamides by aqueous alkalis varies greatly. Methylnitrosourea **(1)** is hydrolyzed rapidly by aqueous KOHβsolutions at low temperatures to give a high yield of diazomethane. Under similar conditions, __N,N__β²βdimethylβ__N,N__β²βdinitroso