The sixth spectrum of tungsten, W VI
β Scribed by F.G. Meijer
- Publisher
- Elsevier Science
- Year
- 1974
- Weight
- 221 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0031-8914
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π SIMILAR VOLUMES
In contrast with the behaviour of many coupling constants. lJ(19%-19~) can change sign. without an accompanying change in the valence of tungsten: the two W-F coupling constants have the same sign in MeOWF5 and related compounds, but they have opposite signs in the WOF< anion.
## Abstract The UV./VIS. absorption spectrum of [18]annulene has been remeasured in 3βrnethylpentane at room and at liquid nitrogen (glass) temperature and interpreted by the CNDO/SβCIβmethod. The confrontation of the experimental electronic transitions with the CNDO/SβCIβcalculated ones favors a s