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cis-dioxobis(2,3-naphthalenedithiolato)tungsten(VI) and the related 1,2-benzenedithiolato complex: Models of tungsten oxidoreductases

✍ Scribed by Akira Nakamura; Hiroyuki Oku; Norikazu Ueyama


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
45 KB
Volume
59
Category
Article
ISSN
0162-0134

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## Abstract The mono‐electronic reduction of __tris__(benzene‐1,2‐dithiolato)Mo(VI) and W(VI) complexes (ML~3~: M = Mo, W; L = S~2~C~6~H^2βˆ’^~4~, S~2~C~6~H~3~CH^2βˆ’^~3~) to their anionic forms ML^βˆ’^~3~ by L(+)‐ascorbic acid (H~2~A) has been studied in tetrahydrofurane (THF):water and THF:methanol by