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The Silicon-Assisted Aza-[2,3]-Wittig Sigmatropic Rearrangement †

✍ Scribed by Anderson, James C.; Siddons, D. Craig; Smith, Stephen C.; Swarbrick, Martin E.


Book ID
127081501
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
153 KB
Volume
61
Category
Article
ISSN
0022-3263

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The aza-[2,3]-Wittig sigmatropic rearran
✍ James C Anderson; Philippe Dupau; D Craig Siddons; Stephen C Smith; Martin E Swa 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 134 KB

The aza-[2,3]-Wittig sigmatropic rearrangement of Z(C)-alkenes can be achieved through the use of a trimethylsilyl anion stabilising group. The major diastereoisomer complements previous results and allows access to each diastereoisomer of the homoallylic amine products. A transition state model is