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The selective functionalization of saturated hydrocarbons. Part 40. Aspects of FeII based peroxide fragmentation in pyridine solution

✍ Scribed by Derek H.R. Barton; Franck Launay

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
703 KB
Volume
53
Category
Article
ISSN
0040-4020

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πŸ“œ SIMILAR VOLUMES

The selective functionalization of satur
The selective functionalization of saturated hydrocarbons. Part 38. Bis(trimethylsilyl) peroxide: an efficient oxidant for the functionalization of hydrocarbons involving the FeII-FeIV manifold.
✍ Derek H.R. Barton; BΓ©atrice M. Chabot πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 552 KB

The selective functionalization of alkane was achieved in a good yield. by a simple Fe"Clz salt and bis(trimethylsily1) peroxide in pyridine. Unlike the Fen-HZ02 system, no extra ligand was needed. The presence of a carbon radical from the Fen-Few manifold was proposed to explain the results.

The selective functionalization of satur
The selective functionalization of saturated hydrocarbons. Part 47. Investigation of the size of the reagent involved in the FeII–FeIV manifold
✍ Derek H.R. Barton; Franck Launay πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 397 KB

Competition experiments between cyclohexane and various aromatic substrates have been carried out in pyridine-acetonitrile in order to ascertain the steric requirements of the FeI~-H202 reagent in comparison with the Fem-H202 reagent already studied. The latter is distinctly larger and much less rea

The selective functionalization of satur
The selective functionalization of saturated hydrocarbons. Part 45. The effect of lower temperature on the rate and efficiency of formation of oxidized products in the FeIII-FeV and FeII-FeIV manifolds
✍ Derek H.R. Barton; Tingsheng Li; Eric Peralez πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 480 KB

In the Fem-Fe v manifold the formation of the iron-carbon bond was found to be very fast, but the evolution to give ketone was slow at -20 \*C and -40 \*C. However, the efficiency at the latter temperature was good. The iron-carbon bond can be captured rapidly by I" or by PhSeH. We have confirmed th