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The selective functionalization of saturated hydrocarbons. Part 38. Bis(trimethylsilyl) peroxide: an efficient oxidant for the functionalization of hydrocarbons involving the FeII-FeIV manifold.

✍ Scribed by Derek H.R. Barton; Béatrice M. Chabot

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
552 KB
Volume
53
Category
Article
ISSN
0040-4020

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✦ Synopsis

The selective functionalization of alkane was achieved in a good yield. by a simple Fe"Clz salt and bis(trimethylsily1) peroxide in pyridine. Unlike the Fen-HZ02 system, no extra ligand was needed. The presence of a carbon radical from the Fen-Few manifold was proposed to explain the results.

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