The selective functionalization of saturated hydrocarbons. Part 45. The effect of lower temperature on the rate and efficiency of formation of oxidized products in the FeIII-FeV and FeII-FeIV manifolds

✍ Scribed by Derek H.R. Barton; Tingsheng Li; Eric Peralez

• Publisher: Elsevier Science
• Year: 1998
• Tongue: French
• Weight: 480 KB
• Volume: 54
• Category: Article
• ISSN: 0040-4020
• DOI: 10.1016/s0040-4020(98)00907-7

✦ Synopsis

In the Fem-Fe v manifold the formation of the iron-carbon bond was found to be very fast, but the evolution to give ketone was slow at -20 *C and -40 *C. However, the efficiency at the latter temperature was good. The iron-carbon bond can be captured rapidly by I" or by PhSeH. We have confirmed that either way to measure the iron-carbon bond ~i,'ves essentially the same results. In contrast to the Fem-Fe v manifold the o fl tv reactions at -20 C in the Fe -Fe manifold are very fast for both iron-carbon bond formation and evolution to final products. In this manifold the reactions at -20 °C are more efficient than those at -5 *C.