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The secondary hydrogen isotope effect

โœ Scribed by E.A. Halevi

Publisher
Elsevier Science
Year
1960
Weight
530 KB
Volume
7
Category
Article
ISSN
0020-708X

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๐Ÿ“œ SIMILAR VOLUMES

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Secondary kinetic isotope effects occur in radical additions to deuterated olefins. Substitution of a deuterium at a carbon undergoing an sp2 to sp3 hybridization-change during reaction, Cg in eq. ( I ) , leads to an The effect at a carbon going from a n olefinic to a radical center, C, in eq. (I),

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Hydrogen/deuterium abstraction by chlorine atoms from gaseous ethyl chlorides. Secondary kinetic isotope effects in the system CH3CH2Cl, CH3CHDCl, CH3CD2Cl
โœ J. Niedzielski; E. Tschuikow-Roux; T. Yano ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 543 KB

The abstraction of hydrogen/deuterium from CH3CH2C1, CH,CHDCl, and CH,CD,Cl by photochemically generated ground-state chlorine atoms has been investigated over the temperature range of 8-94ยฐC using methane as a competitor. Rate constant data for the following reactions have been obtained: (1) CH,C&C