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Secondary hydrogen isotope effect in a gas-phase equilibrium

โœ Scribed by Peter Love; Robert W. Taft Jr.; Thomas Wartik

Publisher
Elsevier Science
Year
1959
Tongue
French
Weight
138 KB
Volume
5
Category
Article
ISSN
0040-4020

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Infrared speatra>of hydrazinium hydrogen oxalate, N2H6HC20a, and of its deuterated derivative, N2D6DC20 , have heemstudied at liquid nitrogen temperature in the 3600 to 200 cm-1 range. It appears that t % e symmetric 0.. H.. 0 hydrogen bond of the hydrogen oxslate chains becomes asymmetric