The Scope of Catalytic Enantioselective Tandem Carbonyl Ylide Formation—Intramolecular [3 + 2] Cycloadditions.
✍ Scribed by David M. Hodgson; Agnes H. Labande; Francoise Y. T. M. Pierard; Maria A. Exposito Castro
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 159 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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## Abstract The first successful example of the enantioselective intermolecular 1,3‐dipolar cycloaddition of a chiral dirhodium(II) catalyst‐associated carbonyl ylide with an aromatic aldehyde dipolarophile is described. The tandem carbonyl ylide formation/cycloaddition reactions of 1‐diazo‐5‐aryl‐