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One-Pot Cross-Metathesis/Tandem Carbonyl Ylide Formation — Intramolecular Cycloaddition of an Unsaturated 2-Diazo-3,6-diketoester.

✍ Scribed by David M. Hodgson; Deepshikha Angrish; Agnes H. Labande


Publisher
John Wiley and Sons
Year
2006
Weight
22 KB
Volume
37
Category
Article
ISSN
0931-7597

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## Abstract Chemoselective cross‐metathesis of unsaturated α‐diazo‐β‐keto esters using Grubbs’ 2^nd^ generation catalyst, followed by Rh~2~(OAc)~4~‐catalysed tandem carbonyl ylide formation‐intramolecular cycloaddition is demonstrated. The two different catalytic metallocarbene transfer reactions h