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Oxapolycycles from One-Pot Cross-Metathesis/Carbonyl Ylide Formation—Intramolecular Cycloaddition of α-Diazo-β-keto Esters.

✍ Scribed by David M. Hodgson; Deepshikha Angrish

Publisher
John Wiley and Sons
Year
2007
Weight
39 KB
Volume
38
Category
Article
ISSN
0931-7597

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Oxapolycycles from One-Pot Cross-Metathe
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✍ David M. Hodgson; Deepshikha Angrish 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 114 KB 👁 2 views

## Abstract Chemoselective cross‐metathesis of unsaturated α‐diazo‐β‐keto esters using Grubbs’ 2^nd^ generation catalyst, followed by Rh~2~(OAc)~4~‐catalysed tandem carbonyl ylide formation‐intramolecular cycloaddition is demonstrated. The two different catalytic metallocarbene transfer reactions h

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