✦ LIBER ✦

The salt of l-prolinium picrate

✍ Scribed by Zhi Min Jin; Yuan Jiang Pan; Mao Lin Hu; Liang Shen; Mei Chao Li

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 158 KB
Volume: 38
Category: Article
ISSN: 0232-1300
DOI: 10.1002/crat.200310129

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

A crystalline salt of prolinium picrate, C~11~H~12~N~4~O~9~, has been prepared and characterized by X‐ray crystallography. The salt crystallizes in orthorhombic space group P2~1~2~1~2~1~ with a = 6.325(1)Å, b = 9.269(1)Å, c = 24.379(4)Å, V = 1429.4(5)Å^3^, Z = 4. In the title salt, the picrate and prolinium ion are held by different bifurcated hydrogen bonds of N‐H—O type, and stablized by bifurcated hydrogen bonds of CH—O type. There exists a competion between hydrogen bonds and π–π stacking in determining the title crystal. (© 2003 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

📜 SIMILAR VOLUMES

Thermochemistry of picrates. III. Enthal

Thermochemistry of picrates. III. Enthalpies of solution and solubities of picrate salts

✍ Arthur Finch; Ann E. Smith 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 429 KB

l-Prolinium trichloroacetate at 105 K

✍ Rajagopal, K. ;Krishnakumar, R. V. ;Mostad, A. ;Natarajan, S. 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 341 KB

l-Valinium picrate

✍ Anitha, K. ;Sridhar, B. ;Rajaram, R. K. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 295 KB

l-Asparaginium picrate

✍ Anitha, K. ;Athimoolam, S. ;Rajaram, R. K. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 371 KB

ÁC 6 H 2 N 3 O 7 À , the two ions are connected by strong asymmetric O-HÁ Á ÁO hydrogen bonds. The cation is involved in a Z1 (zigzag) head-to-tail sequence along the b axis. The torsion angle 21 corresponds to a cis conformation. Hydrophobic layers across z = 1 2 are sandwiched between hydrophilic

l-Leucine l-leucinium picrate

✍ Anitha, K. ;Athimoolam, S. ;Rajaram, R. K. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 350 KB

Growth and characterization of L-prolini

Growth and characterization of L-prolinium tartrate – A new organic NLO material

✍ S. A. Martin Britto Dhas; S. Natarajan 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 141 KB 👁 2 views

Single crystals of L-Prolinium tartrate (C 5 H 10 NO 2 ) + (C 4 H 5 O 6 ) -, a new organic non-linear optical material of size: 15 × 10 × 10 mm 3 were grown using submerged seed solution growth method. Characterization of the crystals was made using single crystal X-ray diffraction and density deter