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Growth and characterization of L-prolinium tartrate – A new organic NLO material

✍ Scribed by S. A. Martin Britto Dhas; S. Natarajan


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
141 KB
Volume
42
Category
Article
ISSN
0232-1300

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✦ Synopsis


Single crystals of L-Prolinium tartrate (C 5 H 10 NO 2 ) + (C 4 H 5 O 6 ) -, a new organic non-linear optical material of size: 15 × 10 × 10 mm 3 were grown using submerged seed solution growth method. Characterization of the crystals was made using single crystal X-ray diffraction and density determination. Spectroscopic, thermal, optical and mechanical studies were carried out. These studies show that the crystals are thermally stable upto 161°C, transparent for the fundamental and second harmonic generation of Nd: YAG (λ = 1064 nm) laser and possess good mechanical strength. Second harmonic generation (SHG) conversion efficiency was investigated to explore the NLO characteristics of this material using Kurtz and Perry method and it was found that the SHG conversion efficiency is about 90% of that of the standard KDP crystals. Laser damage threshold study was also carried out.


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