The extended stretch-bender Hamiltonian, incorporating spin-orbit coupling and overall rotation, has been used to calculate the spin-vibronic structure of the X 2 B 1 state of NH 2 up to the barrier to linearity of this state. A detailed comparison has been made with experimental measurements of the
The rovibronic energies of the SiNSi radical in its electronic state
✍ Scribed by P.R. Bunker; R. Guérout; Z.J. Jakubek; Per Jensen; S.N. Yurchenko
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 98 KB
- Volume
- 795
- Category
- Article
- ISSN
- 0022-2860
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📜 SIMILAR VOLUMES
The extended stretch-bender Hamiltonian, incorporating spin-orbit coupling and overall rotation, has been used to calculate the spin-vibronic structure of the rovibronic energies in the region where the vibronic states of the excited à 2 A 1 electronic state of NH 2 interact with near-resonant high-
The infrared spectrum of the AsO radical in its \({ }^{2} \mathrm{Il}\) ground state has been measured using a diode laser spectrometer. Rovibrational transitions of the fundamental and a number of hot bands were measured in both \({ }^{2} \Pi_{3 / 2}\) and the \({ }^{2} I_{1 / 2}\) substates to an
The ground-state geometrical structure of the heptafulvalene trianion radical, calculated by using the semiempirical open-shell SCF MO method, is found to be of Czv symmetry.
The à Að 1 A 0 Þ $ X X ð 1 A 00 ) spectroscopy of jet-cooled CBrCl has been measured by both laser-induced fluorescence excitation and dispersed fluorescence. All three vibrational frequencies were assigned and measured in both electronic states, including the first gas phase measurements of the C-C