Symmetry doubling of the rovibronic levels in the excited electronic states of CuF
β Scribed by J.M Delaval; J Schamps; C Dufour
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 633 KB
- Volume
- 137
- Category
- Article
- ISSN
- 0022-2852
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Microwave-optical double resonance experiments have been carried out on the JO,, rotational levels of the 4' A'A, excited state of thioformaldehyde (HaCS). The number of microwave transitions to high rovibronic levels of the ground state observed in a given frequency range increases in a roughly lin
The alX+-X3II separation is estimated to be 1804-110 cm -m, which is in reasonable agreement with the recent experimental determination that the separation in a neon matrix is between 15 and 182 cm-I. Th~ calculated spectroscopic constants for the excited states confirm the experimental assignment f