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The rotationally resolved G0+u ← A0+g electronic spectrum of the (202Hg)2 excimer

✍ Scribed by W. Kedzierski; J. Supronowicz; A. Czajkowski; M.J. Hinek; J.B. Atkinson; L. Krause

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
414 KB
Volume
218
Category
Article
ISSN
0009-2614

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✦ Synopsis

Isotopically pure 'O*Hg vapor contained in a quartz cell, was irradiated with frequencydoubled 5140 A output from an Ar+ laser, which caused the formation of Hg,AO,' excimer molecules by photoassociation. Simultaneous probe radiation from a ring dye laser scanned over a range 5400-6000 A, produced the GO: +AO: excitation spectrum which consists of several hundred well-resolved rotational components that have not been previously observed. Two vibronic bands were subjected to a rotational analysis which yielded spectroscopic constants that are compared with some previously reported values.

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