𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The 0+u(6 3P1)←X0+g spectrum of Hg2 excited in a supersonic jet

✍ Scribed by J. Koperski; J.B. Atkinson; L. Krause

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
709 KB
Volume
219
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

The 0,' (6 'PI ) +-X0: excitation spectrum of Hgz van der Waals molecules, produced in a pulsed free-jet supersonic expansion beam crossed with a pulsed dye-laser beam, was studied using He as a carrier gas. A well-resolved structure, arising from transitions between the vibrational levels of the lower and upper states, was recorded at various beam conditions. An analysis of the spectrum yielded the vibrational constants, dissociation energies, and the difference between the equilibrium internuclear separations for the molecule in the two electronic states.

📜 SIMILAR VOLUMES

TheG0u+(61P1)–X0G+Excitation and Fluores
TheG0u+(61P1)–X0G+Excitation and Fluorescence Spectra of Hg2Excited in a Supersonic Jet
✍ J. Koperski; J.B. Atkinson; L. Krause 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 217 KB

The G0 / u (6 1 P 1 ) -X 0 / g excitation and fluorescence spectra of Hg 2 van der Waals molecules, produced in a pulsed free-jet supersonic expansion beam crossed with a pulsed dye-laser beam, were studied using Ar as the carrier gas. A well-resolved vibrational structure of the G0 / u R X 0 / g ex

The rotationally resolved H1u ← A0g± ele
The rotationally resolved H1u ← A0g± electronic spectrum of Hg2
✍ A. Czajkowski; W. Kedzierski; J.B. Atkinson; L. Krause 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 321 KB

Isotopically pure 2°2Hg vapor, contained in a quartz cell, was irradiated with the 2572•5 ,~ output from a frequency-doubled Ar + laser, which produced Hg 2 A0g ~ excimer molecules by photoassociation followed by collisional relaxation• Simultaneously applied probe radiation from a ring laser, scann

The a3Σ+u(a11u → X1Σ+g(X0+g) Transition
The a3Σ+u(a11u → X1Σ+g(X0+g) Transition of Bi2
✍ R. Breidohr; K.D. Setzer; O. Shestakov; E.H. Fink; W. Zyrnicki 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 576 KB

The \(a^{3} \Sigma_{\mathrm{u}}^{+}\left(a_{1} 1_{\mathrm{u}}\right) \rightarrow X^{1} \Sigma_{\mathrm{B}}^{+}\left(X 0_{\mathrm{B}}^{+}\right)\)near-infrared transition of \(\mathrm{Bi}_{2}\), which was recently observed in the thermal emission spectrum of bismuth vapor by Barrow et al. (Chem. Phys

Vibronic coupling and intramolecular dyn
Vibronic coupling and intramolecular dynamics of pyrene as revealed by the S0→S2 excitation spectrum in a supersonic jet
✍ Nobuhiro Ohta; Hiroaki Baba; Giancarlo Marconi 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 664 KB

The fluorescence excitation spectrum of pyrene obtained in a supersonic jet for the S ,\_,-+Sz transition shows a complicated structure due to the interaction of discrete levels of S, with the quasi-continuous levels belonging to S,. The intensity distribution pattern in this region has been evaluat

The 2B1(K′ = 1)-X̃2A1(K″ = 0) subbands o
The 2B1(K′ = 1)-X̃2A1(K″ = 0) subbands of NO2 found in the excitation spectrum using a supersonic molecular beam
✍ Nobuo Sugimoto; Sanzo Takezawa 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 244 KB

-0) subbands at 4641 and 445.6 nm are idenlified in the fluorescence exciralion specua or NO, roIa1ionally cooled in a supersonic jet. The origins of both bands agree well with a calculakm based on rhe theory of Ihe Renner-Teller effect. and the Mbrarional signmenu ui = 14 and 16 are given IO the up