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Rotational Analysis of theH1u←A0g±(1, 0) Bands of (202Hg)2

✍ Scribed by A. Czajkowski; W. Kedzierski; J.B. Atkinson; L. Krause

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
516 KB
Volume
181
Category
Article
ISSN
0022-2852

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✦ Synopsis

Isotopically pure 202 Hg vapor, contained in a quartz cell, was irradiated with the 2572.5-A ˚output from a frequencydoubled Ar / laser, which produced Hg 2 A0 { g excimer molecules by photoassociation followed by collisional relaxation. Simultaneously applied probe radiation from a ring laser, scanned over the range 4150-4400 A ˚, gave rise to the H1 u R A0 { g £ Å 1 R £Љ Å 0 excitation bands consisting of about 490 rotational components. The bands were subjected to a rotational analysis which yielded spectroscopic constants that are compared with some previous data.

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