The rotational spectrum of methacrylonitrile: Dipole moment, internal rotation, and centrifugal distortion
✍ Scribed by J.C. López; J. Demaison; A. Gomez; J.L. Alonso; G. Wlodarczak
- Book ID
- 107802594
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 593 KB
- Volume
- 141
- Category
- Article
- ISSN
- 0022-2852
No coin nor oath required. For personal study only.
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The rotational spectra of both \(\mathrm{CH}_{2}=\mathrm{CHPH}_{2}\) and \(\mathrm{CH}_{2}=\mathrm{CHPD}_{2}\) have been measured from 8 to \(320 \mathrm{GHz}\). Rotational constants, centrifugal distortion constants, and dipole moment components have been determined. Only the gauche form (dihedral
The microwave spectra of sym-CHa DCHO and sym\_CHDaCHO have been measured. In the ground torsional state, the spectra correspond to localised conformers with only a small amount of sym-asym coupling. Apphcation of Watson's reduced haniltonia~ has enabled precise distortion constants free from intern