The rotational spectrum of acetone: Internal rotation and centrifugal distortion analysis
β Scribed by J.M. Vacherand; B.P. Van Eijck; J. Burie; J. Demaison
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 537 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0022-2852
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The theoretical part of the research, performed in Budapest, Hungary, was partially supported by grants from the Scientific Research Foundation of Hungary (OTKA 2101 and FO13962). G.W. and J.D. thank the A.T.P. "PlanΓ©tologie" (CNRS) for financial support.
The microwave spectra of sym-CHa DCHO and sym\_CHDaCHO have been measured. In the ground torsional state, the spectra correspond to localised conformers with only a small amount of sym-asym coupling. Apphcation of Watson's reduced haniltonia~ has enabled precise distortion constants free from intern