✦ LIBER ✦

The Rotational Spectrum of Propene: Internal Rotation Analysis and ab Initio and Experimental Centrifugal Distortion Constants

✍ Scribed by G. Wlodarczak; J. Demaison; N. Heineking; A.G. Csaszar

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 391 KB
Volume: 167
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1994.1231

No coin nor oath required. For personal study only.

✦ Synopsis

The theoretical part of the research, performed in Budapest, Hungary, was partially supported by grants from the Scientific Research Foundation of Hungary (OTKA 2101 and FO13962). G.W. and J.D. thank the A.T.P. "Planétologie" (CNRS) for financial support.

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syn-2-Nitrosopropene was generated, in the gas phase, by chemical reaction of 1-chloro-2-(hydroxyimino)propane with K 2 CO 3 and identified by microwave spectroscopy. The microwave spectrum of the reaction product was observed in the frequency range from 8.0 to 40.0 GHz. The rotational constants (MH