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The role of the homogenous and heterogeneous components of ziegler catalysts in the development of polymerization activity

✍ Scribed by Váradi, J. ;Czájlik, I. ;Baán, A. ;Chirkov, N. M. ;Tsvetkova, V. I.

Book ID
105340188
Publisher
Wiley (John Wiley & Sons)
Year
2007
Weight
343 KB
Volume
16
Category
Article
ISSN
0449-2994

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✍ Roberto Fusco; Luca Longo; Francesco Masi; Fabio Garbassi 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 420 KB 👁 1 views

## Abstract The thermodynamics of the reaction of an ethylene molecule with the Cp~2~TiCH~3~Cl/Al(CH~3~)~2~Cl system (Cp = η~5~‐C~5~H~5~), as a model for olefin polymerization with homogeneous Ziegler‐Natta catalysts, was investigated via quantum mechanical DFT calculations. The comparison of the c