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The role of the heterogeneous component in stereospecific polymerization in the presence of Ziegler-natta catalysts

✍ Scribed by K.S. Minsker; G.T. Fedoseyeva; G.A. Razuvayev


Book ID
118355817
Publisher
Elsevier Science
Year
1963
Weight
320 KB
Volume
4
Category
Article
ISSN
0032-3950

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Grignard reagent PhMgCl was added during the preparation of the catalyst system MgCl 2 /di-n-butyl phthalate (DNBP)/TiCl 4 {AlEt 3 /diphenyl dimethoxyl silane (DPDMS) to improve its performance. It was found that PhMgCl could enhance both the activity of the catalyst and the isotacticity of the prod