The role of mixing time in 2D heteronuclear NOE experiments
✍ Scribed by Katalin E Kövér; Gy Batta
- Publisher
- Elsevier Science
- Year
- 1986
- Weight
- 245 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0022-2364
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Nuclear Overhauser effects (NOE) between protons and heteronuclei can be of great value for the assignment of quaternary nuclei, and they can be very informative and unique in view of stereochemistry and molecular dynamics. The application of a modified 2D-NMR experiment for the assignment of quater
With gradient selected HSQC-NOESY spectra it is possible to detect the NOE e †ect between protons which have the same chemical shift either due to symmetry or due to accidental overlap. The discrimination of the equivalent sites is achieved by allowing one site to couple with 13C in natural abundanc