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The role of electrostatic interactions in the series: S2N2, S4N4, (SN)x

โœ Scribed by A.J. Epstein; N.O. Lipari

Book ID
103771388
Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
274 KB
Volume
56
Category
Article
ISSN
0375-9601

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๐Ÿ“œ SIMILAR VOLUMES

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SCFโ€“Xฮฑโ€“SW calculations have been carried out for SN, S2N2, and S4N4 as well as the analogous oxides NO and N2O2. The electronic charge distribution of the sulfides is remarkably uniform leading to highly polar SN bonds (โˆผS+1/2Nโˆ’1/2) in contrast to the oxides where the NO bonds involve less charge tr

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## Abstract The title reaction, which is spinโ€forbidden for N~2~(X^1^โˆ‘) + NO(X^2^ฮ ) production, has been studied from 960 to 1130 K in a highโ€temperature photochemistry reactor. No reaction could be observed, indicating __k__ < 1 ร— 10^โˆ’15^ cm^3^ molecule^โˆ’1^ s^โˆ’1^. It is concluded that there is no