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The role of alkali halides in the enantioselective hydrogenation of a prochiral keto compound over modified nickel catalysts

✍ Scribed by Lein J. Bostelaar; Wolfgang M.H. Sachtler


Publisher
Elsevier Science
Year
1984
Weight
589 KB
Volume
27
Category
Article
ISSN
0304-5102

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The effects of a co-modifier and carboxylic acid on the hydrogenation rate and the enantio-differentiating ability (e.d.a.) were studied for the hydrogenation of 2-octanone and methyl acetoacetate over a tartaric acid modified reduced nickel catalyst. For the hydrogenation of 2-octanone, tartaric ac