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The enantioselective hydrogenation of methylacetoacetate over nickel catalysts modified with tartaric acid.

โœ Scribed by Alan Bennett; Sheena Christie; Mark A Keane; Robert D. Peacock; Geoffrey Webb


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
537 KB
Volume
10
Category
Article
ISSN
0920-5861

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Studies of co-modifier and carboxylic ac
โœ Tsutomu Osawa; Yuki Nakagawa; Masashi Ando; Tadao Harada; Osamu Takayasu ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 185 KB

The effects of a co-modifier and carboxylic acid on the hydrogenation rate and the enantio-differentiating ability (e.d.a.) were studied for the hydrogenation of 2-octanone and methyl acetoacetate over a tartaric acid modified reduced nickel catalyst. For the hydrogenation of 2-octanone, tartaric ac