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The role of 4′-phosphopantetheine in the biosynthesis of fatty acids, polyketides and peptides

✍ Scribed by Horst Kleinkauf

Book ID
112010314
Publisher
IOS Press
Year
2000
Tongue
English
Weight
20 KB
Volume
11
Category
Article
ISSN
0951-6433

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Decarboxylative acylation of thiolmalona
Decarboxylative acylation of thiolmalonate. A model for the biosynthesis of fatty acids and polyketides
✍ Yoshiaki Kobuke; Jun-ichi Yoshida 📂 Article 📅 1978 🏛 Elsevier Science 🌐 French ⚖ 214 KB

In the biosynthesis of fatty acids and polyketides, 1 the malonyl group attached to one of the two sulfhydryl groups (so called "central" SH-group) in the multienzyme complex is decarboxylatively acylated by the acetyl residue attached to the other ("peripheral" SH-group), giving rise to acetothiol